Resumo

ARANCIBIA, Alejandra; LEIVA, Ana María  e  LOEB, Bárbara. Synthesis and Characterization of New Ruthenium Complexes With 11-carboxy-dipyrido (3,2-a:2’,3’-c)phenazine as Ligand. Bol. Soc. Chil. Quím. [online]. 2000, vol.45, n.4, pp.587-592. ISSN 0366-1644.  http://dx.doi.org/10.4067/S0366-16442000000400010.

A general method for the synthesis of Ruthenium(II) complexes of the type [(HOOC-dppz)₂RuX₂] and [(HOOC-dppz)RuL₂](PF₆)₂ (X = Cl- or SCN-, L = 2,2'-dipyridine or 4,4'-dimethyl-2,2'-dipyridine and HOOC-dppz = 11-carboxy-dipyrido(3,2-a:2',3'-c)phenazine), is reported. The complexes were characterized by conventional technics as UV-Visible, IR and 1H-NMR spectroscopies and cyclic voltammetry.

Palavras-chave : carboxy-dppz; synthesis; Ruthenium complexes; acid group.