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Boletín de la Sociedad Chilena de Química

Print version ISSN 0366-1644

Abstract

CASTILLO, A.; BARICELLI, P.J.; PARDEY, A.J.  and  MOYA, S.A.. CATALITIC OXIDATION OF 1-HEXENE WITH MOLECULAR OXYGEN BY THE Cu(CH3CN)2(NO2)2/Pd(CH3CN)2Cl2 BIMETALLIC SYSTEM. Bol. Soc. Chil. Quím. [online]. 2001, vol.46, n.1, pp.3-8. ISSN 0366-1644.  http://dx.doi.org/10.4067/S0366-16442001000100002.

This work describes the study of the oxidation reaction of 1-hexene to oxygenated compounds homogeneous catalyzed by the bimetallic system, Cu(CH3CN)2(NO2)2/Pd(CH3CN)2Cl2 dissolved in acetonitrile/chloroform under oxygen pressure (1-20 atm) at 55-100 ºC. The results show that 2-hexanone and 3-hexanone are the only oxygenated products formed at 55 ºC. Other oxygenated products such as 2-methyl-3-propyl-oxyrane, 2,3-diethyl-oxyrane and butyl-oxyrane were also observed, beside of the above mentioned at temperatures higher than 55 ºC

Keywords : 1-Hexene; copper catalyst; oxidation reaction.

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