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Journal of the Chilean Chemical Society

On-line version ISSN 0717-9707

Abstract

AGUILA, SERGIO; ALARCON, JULIO; CONEJEROS, CAROLINA  and  ALDERETE, JOEL B. REGIO AND STEREOSELECTIVE HYDROXYLATION OF 5a-HYDROXY-14-EUDESM-11-EN-3-ONE EUDESMANE BY BIOTRANSFORMATION OF RHIZOPUS NIGRICANS. J. Chil. Chem. Soc. [online]. 2006, vol.51, n.2, pp.855-857. ISSN 0717-9707.  http://dx.doi.org/10.4067/S0717-97072006000200004.

This paper describes a combined synthesis of b-hydroxy-sesquiterpen eudesmane derivative using a microbiological hydroxylation sesquiterpen eudesmane derivative as the key reaction. The stereochemistry of the biohydroxylation was identified using mono and bi-dimensional 1H-NMR experiments

Keywords : Biotransformation; Sesquiterpenes; Stereoselective Hydroxylation; Agarofurans.

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