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Journal of the Chilean Chemical Society

On-line version ISSN 0717-9707

Abstract

OZKULA, GULSAH et al. ARSENIC SORPTION USING MIXTURES OF ION EXCHANGE RESINS CONTAINING N-METHYL-D-GLUCAMINE AND QUATERNARY AMMONIUM GROUPS. J. Chil. Chem. Soc. [online]. 2016, vol.61, n.1, pp.2752-2756. ISSN 0717-9707.  http://dx.doi.org/10.4067/S0717-97072016000100001.

The method of synthesis and the arsenie removal properties of ion-exehange resins based on N-methyl-D-glueamine and trimethylammonium groups are presented. The N-methyl-D-glueamine based monomer was synthesized by the reaetion of 4-vinyl benzyl ehloride with N-methyl-D-glueamine, along with theuse of N,N-methylene-bis-aerylamide as a erosslinker reagent for polymerization. In addition, poly(4-vinylbenzyl)trimethylammonium was synthesized. Arsenatesorption studies were conducted and the pH effect, kinetics, sorption capacity, and elution performance were studied. The experimental data were fitted to kineticmodels, such as the pseudo-first order and pseudo-second order models. The pseudo-second order model exhibited the best correlation with the experimental data.The Langmuir and Freundlich isotherms were fitted to the experimental data, and the Freundlich isotherm exhibited the best fit.

Keywords : Arsenie; N-methyl-D-glueamine; ion exehange; ion exehange resin mixture.

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