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Journal of the Chilean Chemical Society

On-line version ISSN 0717-9707

Abstract

MAHARRAMOV, Abel M. et al. CRYSTAL STRUCTURE AND HIRSHFELD SURFACE ANALYSIS OF (E)-5-PHENYL-3-((4-(TRIFLUOROMETHYL)BENZYLIDENE)AMINO)THIAZOLIDIN-2-IMINIUM BROMIDE. J. Chil. Chem. Soc. [online]. 2019, vol.64, n.2, pp.4441-4447. ISSN 0717-9707.  http://dx.doi.org/10.4067/S0717-97072019000204441.

In the cation of the title salt, the central thiazolidine ring adopts an envelope conformation. In the crystal N-H⋯Br hydrogen bonds link the components into a bi-dimensional network with the cations and anions stacked parallel to plane (101). The molecular structure shows several positional disorders over -CF3 and thiazolidine fragments and these were modeled. The weak intermolecular interactions in the crystal structure are mainly constituted by H⋯F, H⋯π and H⋯Br. Hirshfeld surface analysis were used to verify the contributions of the different intermolecular interactions.

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